Quantum Principles

  1. Electromagnetic radiation travels in waves, but it interacts with matter in discrete energy transfers via photons. The energy of a photon is proportional to its frequency:
    E = h ν,
    where h is Planck's constant = 6.626 * 10-34 J s.
  2. This quantized transfer of energy explains the spectrum of radiation emitted by a black body: an object which absorbs all radiation incident on it. The radiation increases the thermal motion of the atoms and molecules in the body, which then re-radiates energy in a thermal spectrum. The resulting Planck (black body) distribution of intensity per unit wavelength, as a function of wavelength and temperature (K), is
    I(λ,T) = 2 π h c2 / (λ5 (eh c / (λ kB T) - 1))
    where kB is Boltzmann's constant = 1.381 * 10-23 J / K:

    (The solid normalized curves correspond to the surface temperatures of Sirius A (9200 K), Sol (5800 K) and Betelgeuse (3800 K). The dashed curves are proportional intensities for Sol and Betelgeuse.)
    For a given temperature, the maximum is located at (2.9 * 10-3 m K) / T (Wien's law).
  3. In the photoelectric effect, light incident on a material can free electrons from the material via the momentum transfer from photons:
    p = h / λ.
    If φ energy is required to eject an electron, a potential ΔVs can be applied which will stop the process:
    e ΔVs = h ν - φ
    where ΔVs is the stopping potential and φ is the work function. The frequency corresponding to zero stopping potential is νcutoff: the minimum frequency required to eject an electron. Note that this relationship is independent of intensity.
  4. The Heisenberg uncertainty principle states that
    Δx Δpx ≥ h / (4 π)
    ΔE Δt ≥ h / (4 π)
    Think in terms of the wavelength required to resolve a particle, and the resulting recoil.
  5. We now know four fundamental constants of nature:

    These constants can be combined to set natural scales for our fundamental units:

    (Some sources define these quantities in terms of h / (2 π) instead of h, or 4 π ε0 instead of ε0, but the orders of magnitude are essentially unchanged.)
    LP and tP are often interpreted as the smallest measurable intervals of distance and time; mP is the mass of 5.9989 * 1022 electrons, and qP is the charge on 8.27756 electrons (as defined here).

    It is also interesting to note that these constants can be combined in easy ways so as to "convert" one fundamental unit into any other; in General Relativity (a geometric theory), it is usually convenient to express everything in terms of length, so that

    This suggests that if indeed there is a theory which encompasses all physical phenomena (at least at the smallest scales), that all of the fundamental physics quantities (length, time, mass and charge) will be interrelated.


©2011, Kenneth R. Koehler. All Rights Reserved. This document may be freely reproduced provided that this copyright notice is included.

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